Hydrogenating properties of rhenium chlorides and sulfides |
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Authors: | M A Ryashentseva Kh M Minachev E P Belanova |
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Institution: | (1) Faculty of Chemistry, University of Wrocław, F-Joliot Curie 14, 50-383 Wrocław, Poland |
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Abstract: | 1. |
It was found that trivalent rhenium chloride has a high activity in the hydrogenation of the C=C bonds in cyclohexene, the pyridine ring, and thiophene at 200–270°, a hydrogen pressure of 130–140 atm, and a reaction time of 3 h.
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Rhenium(III) chloride has a higher activity than rhenium heptasulfide in reducing the C=C bond in cyclohexane and the pyridine ring
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