Addition of S-H bonds across electron-deficient olefins catalyzed by well-defined copper(I) thiolate complexes |
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| Authors: | Delp Samuel A Munro-Leighton Colleen Goj Laurel A Ramírez Magaly A Gunnoe T Brent Petersen Jeffrey L Boyle Paul D |
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| Institution: | Department of Chemistry, North Carolina State University, Raleigh, North Carolina 27695-8204, USA. |
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| Abstract: | A series of monomeric (NHC)Cu(SR) (R = Ph or CH2Ph; NHC = N-heterocyclic carbene) complexes have been synthesized and fully characterized including single-crystal X-ray diffraction studies. These complexes catalyze the addition of S-H bonds across electron-deficient olefins to regioselectively produce "anti-Markovnikov" products. |
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