| 钯催化偶联-消去法合成芳基末端炔的研究进展 |
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| 引用本文： | 尹守春,徐洪耀,唐本忠.钯催化偶联-消去法合成芳基末端炔的研究进展[J].应用化学,2004,21(10):973-0. |
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| 作者姓名： | 尹守春 徐洪耀 唐本忠 |
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| 作者单位： | 安徽大学，香港科技大学 |
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| 基金项目： | 国家自然科学基金(50073001,90206014)，安徽省优秀青年基金(04044060)，安徽省教委自然科学基金(2003kj016) |
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| 摘 要： | 钯催化偶联-消去法合成芳基末端炔的研究进展;芳炔;偶联反应;钯催化剂;合成;综述
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| 关 键 词： | 钯催化偶联-消去法合成芳基末端炔的研究进展 芳炔 偶联反应 钯催化剂 合成 综述 |
| 文章编号： | 1000-0518(2004)10-0973-07 |
| 收稿时间： | 2009-06-29 |
| 修稿时间： | 2003年11月19 |
Recent Advances in Synthesis of Terminal Aryl Acetylenes by Palladium-Catalyzed Coupling-Elimination Reaction |
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| YIN Shou Chun,XU Hong Yao.Recent Advances in Synthesis of Terminal Aryl Acetylenes by Palladium-Catalyzed Coupling-Elimination Reaction[J].Chinese Journal of Applied Chemistry,2004,21(10):973-0. |
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| Authors: | YIN Shou Chun XU Hong Yao |
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| Institution: | YIN Shou Chun,XU Hong Yao * |
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| Abstract: | As important organic intermediates, terminal aryl acetylenes have been widely applied in the organic and polymer field. The effect of reactants(alkynylzinc reagents and aryl halides reagent), catalysts(palladium catalyst and cocatalyst) and other reaction conditions on the synthesis of terminal aryl acetylene are reviewed. The reaction mechanisms of palladium catalyzed coupling elimination reaction are discussed, showing that palladium catalyzed coupling elimination reaction is an effective method in the synthesis of the terminal aryl acetylene. |
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| Keywords: | aryl acetylene coupling reaction palladium catalyst synthesis review |
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