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Trace Analysis of Some Bivalent Cations using Peak Focusation Technique with Microcolumn Ion Chromatography
Authors:D Kouřilová  Nguyen Thi Phuong Thao  M Krejči
Institution:Institute of Analytical Chemistry, Czechoslovak Academy of Sciences , Leninova 82, 61142, Brno, Czechoslovakia
Abstract:Abstract

Some conditions for cation focusation on cation resin when using the microcolumn liquid chromatograph with conductometric detection are derived and verified experimentally. Separation is carried out using a complexing agent and a competitive cation in the mobile phase. Cations of transition metals, alkaline earths and lead were analysed. Sensitivity of the method ranges within tenths of p.p.b.
Keywords:Ion chromatography  microcolumn liquid chromatography  bivalent cations
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