| 三价铑催化苯甲酰胺与醌的C–H活化偶联(英文) |
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| 引用本文： | 戚自松,李兴伟.三价铑催化苯甲酰胺与醌的C–H活化偶联(英文)[J].催化学报,2015,36(1):48-56. |
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| 作者姓名： | 戚自松 李兴伟 |
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| 作者单位： | 中国科学院大连化学物理研究所,辽宁大连,116023 |
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| 基金项目： | Chinese Academy of Sciences and the National Natural Science Foundation of China (21272231).基金来源:中国科学院大连化学物理研究所，国家自然科学基金 |
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| 摘 要： | 三价铑在氧化条件下催化N-烷基苯甲酰胺与醌反应生成芳基醌.在氧化还原中性条件下,经过偶联和内酯化反应可以得到2-羟基-6H-苯并c]吡喃-6-酮.
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| 关 键 词： | 三价铑 碳氢活化 苯甲酰胺 芳基醌 |
| 收稿时间： | 2014-09-25 |
Rh(III)-catalyzed C-H activation of benzamides:Coupling with quinones |
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| Zisong Qi
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Xingwei Li.Rh(III)-catalyzed C-H activation of benzamides:Coupling with quinones[J].Chinese Journal of Catalysis,2015,36(1):48-56. |
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| Authors: | Zisong Qi Xingwei Li |
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| Institution: | Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China |
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| Abstract: | Rh(III)-catalyzed C-H activation of N-(alkyl)benzamides in the oxidative coupling with various quinones. In addition, under redox-neutral conditions, 2-hydroxy-6H-benzoc]chromen-6-ones were also obtained via a cascade of cross-coupling followed by lactonization. |
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| Keywords: | Rhodium(III) C-H activation Benzamides Arylquinones |
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