| 钯催化烯丙基磺酰胺的分子内胺氟化反应 |
| |
| 引用本文： | 程家顺,陈品红,刘国生. 钯催化烯丙基磺酰胺的分子内胺氟化反应[J]. 催化学报, 2015, 36(1): 40-47. DOI: 10.1016/S1872-2067(14)60164-9 |
| |
| 作者姓名： | 程家顺 陈品红 刘国生 |
| |
| 作者单位： | 中国科学院上海有机化学研究所金属有机国家重点实验室,上海,200032 |
| |
| 基金项目： | the National Basic Research Program of China，the National Natural Science Foundation of China，the Science and Technology Commission of Shanghai Municipality，the CAS/SAFEA International Partnership Program for Creative Research Teams.基金来源:国家重点基础研究发展计划，国家自然科学基金，上海市科学技术委员会，中国科学院、国家外国专家局创新团队国际合作伙伴计划 |
| |
| 摘 要： | 报道了钯催化的非活性烯烃的胺氟化反应,在酸性添加剂HOAc的作用下,反应以较好的收率和区域选择性地得到6-endo环合产物,实现了氟代的环状磺胺类产物的有效合成.
|
| 关 键 词： | 钯催化 胺氟化 烯烃 氟代1,3-二胺 6-endo环合 |
| 收稿时间： | 2014-05-19 |
Pd-catalyzed intramolecular aminofluorination of allylic sulfamides |
| |
| Jiashun Cheng , Pinhong Chen , Guosheng Liu. Pd-catalyzed intramolecular aminofluorination of allylic sulfamides[J]. Chinese Journal of Catalysis, 2015, 36(1): 40-47. DOI: 10.1016/S1872-2067(14)60164-9 |
| |
| Authors: | Jiashun Cheng Pinhong Chen Guosheng Liu |
| |
| Affiliation: | State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China |
| |
| Abstract: | A facile Pd-catalyzed intramolecular aminofluorination reaction of allylic sulfamides was developed that can be used to prepare fluorinated 1,3-diamine derivatives. Acetic acid was essential for regulation to give the major 6-endo cyclization products. |
| |
| Keywords: | Palladium-catalyzed Aminofluorination Alkene Fluorinated 1,3-diamine 6-Endo cyclization |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
| 点击此处可从《催化学报》浏览原始摘要信息 |
|
点击此处可从《催化学报》下载全文 |
