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Synthesis and properties of a platinum catalyst supported on plasma chemical silicon carbide
Authors:N N Vershinin  V A Bakaev  V I Berestenko  O N Efimov  E N Kurkin  E N Kabachkov
Institution:1.Institute of Problems of Chemical Physics,Russian Academy of Sciences,Chernogolovka,Russia;2.Scientific Center in Chernogolovka,Russian Academy of Sciences,Chernogolovka,Russia;3.Ural Federal Institute,Yekaterinburg,Russia
Abstract:A CO oxidation catalyst based on β–SiC and Pt nanoparticles has been synthesized and studied. The average size of Pt clusters on the surface of the plasma-chemical silicon carbide nanoparticles is close to 4 nm. It has been found that the rate of the CO oxidation reaction at low concentrations (100 mg/m3) in air at room temperature over the catalyst based on platinum and silicon carbide nanoparticles is 60–90 times that over a platinum black-based catalyst with a specific surface area of 30 m2/g. The Pt/SiC catalyst containing 12 wt % Pt has been found to provide the maximum CO oxidation rate.
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