Thermodynamics and mechanism of reduction of silicon with carbon in a crucible reaction |
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| Authors: | V A Grachev |
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| Institution: | 1.Frumkin Institute of Physical Chemistry and Electrochemistry,Russian Academy of Sciences,Moscow,Russia |
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| Abstract: | A thermodynamic analysis of a crucible reaction, which takes place in crucible induction furnaces, has been represented. A new diagram of a crucible reaction, with due account for partial pressures and activities of the participating components, has been suggested. For the first time ever, the electrochemical mechanism of a crucible reaction has been studied; the research has confirmed the correctness of the suggested diagram. |
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