A dynamic supramolecular system exhibiting substrate selectivity in the catalytic epoxidation of olefins |
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Authors: | Jónsson Stefán Odille Fabrice G J Norrby Per-Ola Wärnmark Kenneth |
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Affiliation: | Organic Chemistry 1, Department of Chemistry, Lund University, P.O. Box 124, SE-221 00 Lund, Sweden. |
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Abstract: | A dynamic supramolecular system involving hydrogen bonding between a Mn(III) salen catalyst and a Zn(II) porphyrin receptor exhibits selectivity for pyridine appended cis-beta-substituted styrene derivatives over phenyl appended derivatives in a catalytic epoxidation reaction. |
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