Novel catalytic effects in ester aminolysis in chlorobenzene |
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Authors: | Basilio Nuno García-Río Luís Leis J Ramón Mejuto Juan C Pérez-Lorenzo Moisés |
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Affiliation: | Dpto. Química Física, Facultade de Química, Universidade de Santiago de Compostela, Avda. das Ciencias s/n, 15782 Santiago de Compostela, Spain. |
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Abstract: | The mechanism of glyme catalyzed ester aminolysis in chlorobenzene should be modified by including a new reaction pathway that shows a first-order dependence on the concentration of the phase transfer catalyst and a second-order dependence on butylamine. |
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