Stabilitäten von As(V) in Chlorokomplexen |
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| Authors: | A. Feza Demiray Wolfgang Brockner |
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| Affiliation: | (1) Anorganisch-Chemisches Institut, Technische Universität Clausthal, D-3392 Clausthal-Zellerfeld, Germany |
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| Abstract: | The temperature dependent behaviour of PCl4AsCl6, PCl4SbCl6 and AsCl4SbCl6 has been investigated byRaman spectroscopy. The As(V) containing complexes decompose into homogeneous molecular melts consisting of AsCl3, Cl2 and PCl5, respectively. In PCl4SbCl6 PCl4+ and SbCl6– complex ions were found in the solid as well as in the molten state. |
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| Keywords: | AsCl4SbCl6 Melt PCl4AsCl6 PCl4SbCl6 Raman spectra |
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