Unexpected formation of new fluoroboranes from the reaction of NMe4B3H8 with BF3 and MeC identical with CH: exo-2-FB4H9 and trans-MeCH=CHBF2 |
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| Authors: | Fox Mark A Greatrex Robert Ormsby Daniel L |
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| Affiliation: | Department of Chemistry, University of Durham, South Road, Durham, UK DH1 3LE. |
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| Abstract: | The new fluoroboranes exo-2-FB4H9 1 and trans-MeCH=CHBF2 2 have been obtained unexpectedly and in good yield from the reaction of tetramethylammonium octahydrotriborate (NMe4B3H8) with boron trifluoride and propyne (MeC identical to CH). |
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