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A new Zn(II) coordination polymer with 4-pyridylthioacetate: assemblies of homo-chiral helices with sulfide sites
Authors:Kondo Mitsuru  Miyazawa Makoto  Irie Yasuhiko  Shinagawa Reiko  Horiba Tomonori  Nakamura Akira  Naito Tetsuyoshi  Maeda Kenji  Utsuno Shunji  Uchida Fumio
Affiliation:Department of Chemistry, Faculty of Science, Shizuoka University, 836 Ohya, Shizuoka 422-8529, Japan. scmkond@ipc.shizuoka.ac.jp
Abstract:A coordination polymer [Zn(pyta)(OH)] (pyta = 4-pyridylthioacetate), was synthesized and structurally characterized; it is constructed by an alternating assembly of two types of homo-chiral helices, [Zn-OH] and [Zn-pyta], in which the sulfide moieties are fastened in the latter columns.
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