A new Zn(II) coordination polymer with 4-pyridylthioacetate: assemblies of homo-chiral helices with sulfide sites |
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Authors: | Kondo Mitsuru Miyazawa Makoto Irie Yasuhiko Shinagawa Reiko Horiba Tomonori Nakamura Akira Naito Tetsuyoshi Maeda Kenji Utsuno Shunji Uchida Fumio |
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Affiliation: | Department of Chemistry, Faculty of Science, Shizuoka University, 836 Ohya, Shizuoka 422-8529, Japan. scmkond@ipc.shizuoka.ac.jp |
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Abstract: | A coordination polymer [Zn(pyta)(OH)] (pyta = 4-pyridylthioacetate), was synthesized and structurally characterized; it is constructed by an alternating assembly of two types of homo-chiral helices, [Zn-OH] and [Zn-pyta], in which the sulfide moieties are fastened in the latter columns. |
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