Spectroscopic and crystallographic studies on the stability of self-assembled coordination nanotubes |
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Authors: | Aoyagi Masaru Tashiro Shohei Tominaga Masahide Biradha Kumar Fujita Makoto |
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Institution: | Department of Applied Chemistry, Graduate School of Engineering, University of Tokyo, CREST, Japan Science and Technology Corporation (JST), 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan. |
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Abstract: | On complexation with (en)Pd(NO3)2, tetrakis(3,5-pyridine) ligand gives two isomeric coordination nanotubes, which are in slow equilibrium despite the presence of sixteen Pd-N bonds in the tube framework. |
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