Aqueous emulsion containing fluorous cobalt species in supercritical CO2 for catalytic air oxidation of toluene |
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| Authors: | Zhu Jie Robertson Alan Tsang Shik Chi |
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| Affiliation: | Surface and Catalysis Research Centre, Department of Chemistry, University of Reading, Whiteknights, Reading RG6 6AD, UK. |
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| Abstract: | An aqueous emulsion containing ionic Co2+ and Br- species stabilised by fluorous surfactant-like species in supercritical CO2-air mixture acts as a nano-reactor with excellent interfacial contacts of all necessary hydrophilic/hydrophobic species, which renders safe operation of catalytic aerial oxidation of toluene at high yields. |
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