A twenty-four membered mixed-metal macrocycle; synthesis and structure of cyclo-[(3-Me-1,2-C6H3O2)2SbNa(THF)2]6 |
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Authors: | Paver Michael A Joy Jonathan S Hursthouse Michael B |
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Affiliation: | Department of Chemistry, University of Southampton, Highfield, Southampton, UK SO17 1BJ. M.Paver@soton.ac.uk |
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Abstract: | The first example of a twenty-four membered mixed p-/s-block macrocycle, cyclo-[(3-Me-1,2-C6H3O2)2SbNa(THF)2]6 1 has been synthesised and structurally characterised from the reaction between 3-Me-1,2-C6H3(OH)(ONa) and (Me2N)2Sb(CH2)3Sb(NMe2)2. |
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