Synthesis and aqueous solution properties of a well-defined thermo-responsive schizophrenic diblock copolymer |
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Authors: | Weaver J V M Armes S P Bütün V |
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Affiliation: | School of Chemistry, Physics and Environmental Science, Sussex University, Falmer, Brighton, East Sussex, UK BN1 9QJ. |
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Abstract: | We report only the second example of a thermo-responsive 'schizophrenic' diblock copolymer surfactant: unlike the original (meth)acrylamide-based example reported by Laschewsky and co-workers (J. Am. Chem. Soc., 2002, 124, 3787), this new methacrylate-based diblock copolymer is near-monodisperse, readily synthesized in high yield and exhibits a broad temperature range between the two micelle transitions. |
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