Rhodium-catalysed cyclisation reaction of allenynes with arylboronic acids |
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| Authors: | Miura Tomoya Ueda Keita Takahashi Yusuke Murakami Masahiro |
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| Institution: | Department of Synthetic Chemistry and Biological Chemistry, Kyoto University, Katsura, Kyoto, Japan. |
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| Abstract: | Allenynes having malonate-based tethers reacted with arylboronic acids in the presence of a rhodium(I) catalyst to sequentially form three carbon-carbon bonds, and arylated bicyclic skeletons were constructed in a stereoselective manner. |
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