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Quantitative formation of a tetraporphyrin [2]catenane via copper and zinc coordination
Authors:Beyler Maryline  Heitz Valérie  Sauvage Jean-Pierre
Affiliation:Laboratoire de Chimie Organo-Minérale, LC3 UMR 7177 du CNRS, Université Louis Pasteur, Institut de Chimie, 4 rue Blaise Pascal, Strasbourg Cedex, France.
Abstract:A [2]catenane is formed quantitatively by mixing substituted 1,10-phenanthroline-based chelates with copper(I) acting as central template, the ring-forming reaction being based on the coordination of pyridinic bidentate ligands onto the zinc atoms of the four porphyrins surrounding the core of the molecule.
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