Unusual face-to-face pi-pi stacking interactions within an indigo-pillared M3(tpt)-based triangular metalloprism |
| |
| Authors: | Wu Jing-Yun Chang Che-Hao Thanasekaran P Tsai Chen-Chuan Tseng Tien-Wen Lee Gene-Hsiang Peng Shie-Ming Lu Kuang-Lieh |
| |
| Institution: | Institute of Chemistry, Academia Sinica, Taipei, 115, Taiwan. |
| |
| Abstract: | A triangular metalloprism, ((CO)3Re(mu-2)Re(CO)3)3(mu3-1)2], self-assembled from Re2(CO)10, 2,4,6-tri-4-pyridyl-1,3,5-triazine (tpt, 1), and indigo (H2(2)), represents a fairly novel example of strong face-to-face pi-pi interactions between the central triazine rings of the tpt ligands that bow significantly inward distorting the prismatic structure. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
