| (S)-1,1-二苯基-2-吡咯啶甲醇催化蒽酮与马来酰亚胺的不对称Diels-Alder反应 |
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| 引用本文： | 何龙,刘全忠.(S)-1,1-二苯基-2-吡咯啶甲醇催化蒽酮与马来酰亚胺的不对称Diels-Alder反应[J].合成化学,2006,14(2):190-192. |
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| 作者姓名： | 何龙 刘全忠 |
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| 作者单位： | 西华师范大学,化学化工学院,四川,南充,637002;西华师范大学,化学化工学院,四川,南充,637002 |
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| 基金项目： | 湖北省教育厅人文社会科学基金 |
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| 摘 要： | 研究了(S)-1,1-二苯基-2-吡咯啶甲醇催化蒽酮与马来酰亚胺的不对称D iels-A lder反应,考察了蒽酮与不同N-取代马来酰亚胺的反应。结果表明,在最佳反应条件下化学产率97%,对映选择性44%。
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| 关 键 词： | (S)-1 1-二苯基-2-吡咯啶甲醇 不对称Diels-Alder反应 蒽酮 马来酰亚胺 催化剂 |
| 文章编号： | 1005-1511（2006）02-0190-03 |
| 收稿时间： | 2005-07-29 |
| 修稿时间： | 2005年7月29日 |
Asymmetric Diels-Alder Reactions of Anthrone with Maleimides Catalyzed by (S)-1,1-diphenyl-2-pyrrolidinemethanol |
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| HE Long,LIU Quan-zhong.Asymmetric Diels-Alder Reactions of Anthrone with Maleimides Catalyzed by (S)-1,1-diphenyl-2-pyrrolidinemethanol[J].Chinese Journal of Synthetic Chemistry,2006,14(2):190-192. |
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| Authors: | HE Long LIU Quan-zhong |
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| Institution: | College of Chemistry and Chemical Engineering, China West Normal University, Nanchong 637002, China |
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| Abstract: | Asymmetric Diels-Alder reactions of anthrone with maleimides were catalyzed by(S)-1,1-diphenyl-2-pyrrolidinemethanol.The reaction temperature was optimized and a variety of N-substituted maleimides were examined.A yield of 97% and enantiomeric excess of 44% were achieved under the optimal reaction conditions. |
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| Keywords: | (S)-1 1-diphenyl-2-pyrrolidinemethanol asymmetric Diels-Alder reaction anthrone maleimides catalyst |
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