Transient dimer formation in supercritical carbon dioxide as seen from Raman scattering |
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| Authors: | Cabaço M Isabel Longelin S Danten Y Besnard M |
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| Affiliation: | Centro de Física Atómica da UL, Av Prof Gama Pinto 2, Lisboa, Portugal. isabel@cii.fc.ul.pt |
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| Abstract: | The polarized and depolarized Raman profiles of supercritical CO(2) have been measured in the region of the nu(2) bending mode (forbidden transition at about 668 cm(-1)) and for the Fermi dyad (1285 and 1388 cm(-1)) along the isotherms 307, 309, 313, and 323 K in a reduced density domain 0.04
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