Diastereo- and enantioselective synthesis of alpha,beta-epoxyketones using aqueous NaOCl in conjunction with dihydrocinchonidine derived phase-transfer catalysis at room temperature. Scope and limitations |
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| Authors: | Lygo Barry Gardiner Stuart D McLeod Michael C To Daniel C M |
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| Affiliation: | School of Chemistry, University of Nottingham, Nottingham, UK NG7 2RD. |
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| Abstract: | In this paper we present studies into the scope and limitations of asymmetric PTC epoxidation of enones and the oxidation-epoxidation of allylic alcohols using aqueous NaOCl in conjunction with a dihydrocinchonidine derived quaternary ammonium salt catalyst. |
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