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Acid‐Stable Peroxoniobophosphate Clusters To Make Patterned Films |
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| Authors: | Dr. Jung‐Ho Son Deok‐Hie Park Prof. Douglas A. Keszler Prof. William H. Casey |
| Affiliation: | 1. Department of Chemistry, University of California, Davis, One Shields Ave, Davis, CA 95616 (USA), Fax: (+1)?530‐752‐8995;2. Department of Chemistry, 153 Gilbert Hall, Oregon State University, Corvallis, OR 97331‐4003 (USA);3. Department of Earth and Planetary Science, One Shields Ave, Davis, CA 95616 (USA) |
| Abstract: | Two new peroxoniobophosphate clusters were isolated as tetramethylammonium (TMA) salts having the stoichiometries: TMA5[HNb4P2O14(O2)4]?9 H2O and TMA3[H7Nb6P4O24(O2)6]?7 H2O. The former is stable over the pH range: 3 |
| Keywords: | niobium peroxides phosphorus polyoxometalates synthesis |