Cooperative Dehydrogenation of N‐Heterocycles Using a Carbon Nanotube–Rhodium Nanohybrid |
| |
| Authors: | Dr. Dhanaji V. Jawale Dr. Edmond Gravel Dr. Nimesh Shah Dr. Vincent Dauvois Prof. Dr. Haiyan Li Prof. Dr. Irishi N. N. Namboothiri Dr. Eric Doris |
| |
| Affiliation: | 1. CEA, iBiTecS, Service de Chimie Bioorganique et de Marquage, 91191 Gif‐sur‐Yvette (France);2. Department of Chemistry, Indian Institute of Technology Bombay Mumbai 400 076 (India);3. CEA, DEN, DPC, SECR, LRMO, 91191 Gif‐sur‐Yvette (France);4. State Key Laboratory of Physical Chemistry for Solid Surfaces and National Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers, and Esters, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (P. R. China) |
| |
| Abstract: | Rhodium nanoparticles were anchored on carbon nanotubes and the resulting nanohybrid was studied as co‐catalyst, along with tert‐butylcatechol, for the dehydrogenation of various N‐heterocycles. The co‐catalytic system operates in high yields, under the mildest conditions reported so far, and can be applied to a wide variety of secondary amine‐containing scaffolds. |
| |
| Keywords: | carbon nanotubes co‐catalysis heterogeneous catalysis nanoparticle |
|
|
