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Sandwich‐Structured Graphene–Nickel Silicate–Nickel Ternary Composites as Superior Anode Materials for Lithium‐Ion Batteries
Authors:Renxi Jin  Yang Yang  Yunfeng Li  Xianchun Liu  Prof Yan Xing  Dr Shuyan Song  Prof Zhan Shi
Institution:1. Department of Chemistry, Northeast Normal University, Changchun 130024 (P.R. China), Fax: (+86)?431‐85099108;2. State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130012 (P.R. China);3. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry of Jilin University, Changchun 130022 (P.R. China)
Abstract:We report the synthesis of sandwich‐structured graphene–nickel silicate–Ni ternary composites by using the solvothermal method followed by a simple in situ reduction procedure. The composites show an interesting structure with graphene sandwiched between two layers of well‐dispersed Ni nanoparticles (NPs) anchored on ultrathin nickel silicate nanosheets. These ternary composites exhibit enhanced performance as anode materials owing to the synergistic effect between the graphene matrix and electrochemically inert Ni nanoparticles, an effect that holds promise for the design and fabrication of other advanced electrode materials.
Keywords:anode material  nanostructures  silicates  solvothermal synthesis  ternary composites
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