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Hexametaphosphate‐Capped Silica Mesoporous Nanoparticles Containing CuII Complexes for the Selective and Sensitive Optical Detection of Hydrogen Sulfide in Water
Authors:Sameh El Sayed  Dr. Michele Milani  Prof. Maurizio Licchelli  Prof. Ramón Martínez‐Máñez  Dr. Félix Sancenón
Affiliation:1. Centro de Reconocimiento Molecular y Desarrollo Tecnológico (IDM), Unidad Mixta Universidad Politécnica de Valencia, Universidad de Valencia (Spain);2. Departamento de Química, Universidad Politécnica de Valencia, Camino de Vera s/n, 46022, Valencia (Spain);3. CIBER de Bioingeniería, Biomateriales y Nanomedicina (CIBER‐BBN);4. Dipartimento di Chimica, Università di Pavia via Taramelli 12, 27100 Pavia (Italy)
Abstract:CuII‐macrocycle functionalized hexametaphosphate‐capped silica mesoporous nanoparticles have been prepared and used for the selective and sensitive detection of hydrogen sulfide in aqueous environments. The possibility of using different metal complexes combined with different capping anions and choice of different dyes or other sensing molecules as indicators makes this new protocol highly appealing for the preparation of new sensing systems for sulfide detection in different environments.
Keywords:displacement reaction  gated materials  hydrogen sulfide  sensors  signal amplification
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