Lanthanide Complexes of Azidophenacyl‐DO3A as New Synthons for Click Chemistry and the Synthesis of Heterometallic Lanthanide Arrays |
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| Authors: | Dr Manuel Tropiano Dr Alan M Kenwright Prof Dr Stephen Faulkner |
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| Institution: | 1. Chemistry Research Laboratory, University of Oxford, Mansfield Road, Oxford OX1 3TA (UK);2. Department of Chemistry, University of Durham, South Road, Durham DH1 3LE (UK) |
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| Abstract: | Lanthanide complexes of azidophenacyl DO3A are effective substrates for click reactions with ethyne derivatives, giving rise to aryl triazole appended lanthanide complexes, in which the aryl triazole acts as an effective sensitising chromophore for lanthanide luminescence. They also undergo click chemistry with propargylDO3A derivatives, giving rise to heterometallic complexes. |
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| Keywords: | click reaction energy transfer heterometallic lanthanide luminescence |
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