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Single‐Walled TiO2 Nanotubes: Enhanced Carrier‐Transport Properties by TiCl4 Treatment
Authors:Imgon Hwang  Seulgi So  Mohamed Mokhtar  Abdelmohsen Alshehri  Shaeel A Al‐Thabaiti  Dr Anca Mazare  Prof Patrik Schmuki
Institution:1. Department of Materials Science Engineering, University of Erlangen‐Nuremberg, Martensstrasse 7, 91058 Erlangen (Germany), Fax: (+49)?9131‐852‐7582;2. Department of Chemistry, King Abdulaziz University, Jeddah (Saudi Arabia)
Abstract:In the present work we report significant enhancement of the photoelectrochemical properties of self‐ organized TiO2 nanotubes by a combined “de‐coring” of classic nanotubes followed by an appropiate TiCl4 treatment. We show that, except for the expected particle decoration, a key effect of the TiCl4 treatment is that the electron transport characteristics in TiO2 nanotubes can be drastically improved, for example, we observe an enhancement of up to 70 % in electron‐transport times.
Keywords:anodization  photoanode  photoelectric property  single‐walled  TiO2 nanotubes
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