Syntheses and molecular self-assembly of chiral phosphorami-dates |
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| Authors: | DU Da-Ming HUA Wen-Ting WANG Jian-WuJIN Xiang-LinCollege of Chemistry Molecular Engineering Peking University Beijing China College of Chemistry Shandong University Jinan Shandong China |
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| Affiliation: | DU,Da-Ming HUA,Wen-Ting WANG,Jian-WuJIN,Xiang-LinCollege of Chemistry and Molecular Engineering,Peking University,Beijing 100871,China College of Chemistry,Shandong University,Jinan,Shandong 250100,China |
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| Abstract: | Two chiral phosporamidates, (R)‐(–)‐1, 1′‐binaphthyl‐2, 2′dihydroxy‐N‐ [α‐(S)‐methylbenzyl] phosphoramidate and (–)‐1,1′‐biphenyl‐2,2′‐dihydroxy‐N‐[α‐(S)‐methylbenzyl]‐phosphoramidate were synthesized. Their crystal structures were determined by X‐ray single crystal diffraction analysis. The phosphoramidate molecules are self‐associated by intermolecular N? H ···O = P hydrogen bonds and aromatic edge to face interactions. |
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| Keywords: | Phosphoramidate hydrogen bond crystal structure |
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