| Oxidation of N-benzyl groups |
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| 作者姓名： | 邱文革 陈树森 于永忠 |
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| 作者单位： | School of Chemical Engineering and Materials Science，Beijing Institute of Technology，Beijing 100081，China，School of Chemical Engineering and Materials Science，Beijing Institute of Technology，Beijing 100081，China，School of Chemical Engineering and Materials Science，Beijing Institute of Technology，Beijing 100081，China |
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| 摘 要： | The oxidative reactivity of 2,6,8,12-tetraacetyl-4,10-dibenzy1-2,4,6,8,10,12-hexaazatetracydot5,5.0,05.9.03.11] dodecane (3) in several conditions was studied.It was found that the N-benzyl groups in compound 3 could be oxidized to benzoyi groups byCr(Ⅵ) reagents,and could be removed by cerium ammonium nitrate (CAN),meanwhile nitroamine products were given.
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Oxidation of N-benzyl groups |
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| QIU,Wen-Ge CHEN,Shu-Sen YU,Yong-ZhongSchool of Chemical Engineering and Materials Science,Beijing Institute of Technology,Beijing ,China.Oxidation of N-benzyl groups[J].Chinese Journal of Chemistry,2000,18(5):756-758. |
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| Authors: | QIU Wen-Ge CHEN Shu-Sen YU Yong-ZhongSchool of Chemical Engineering and Materials Science Beijing Institute of Technology Beijing China |
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| Institution: | QIU,Wen-Ge CHEN,Shu-Sen YU,Yong-ZhongSchool of Chemical Engineering and Materials Science,Beijing Institute of Technology,Beijing 100081,China |
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| Abstract: | The additive reactivity of 2,6,8,12‐tetraacetyl‐4, 10‐dibenzyl‐2,4,6,8,10,12‐hexazatetracyclo 5.5.0.05.9. 03.11] dodecane (3) in several conditions was studied. It was found that the N‐benzyl groups in compound 3 could be oxidized to benzoyl groups by Cr(VI) reagents, and could be removed by cerium ammonium nitrate (CAN), meanwhile nitroamine products were given. |
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| Keywords: | Cage compound oxidation debenzylation |
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