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A new class of chiral pyrrolidine ligands for homogeneous catalytic enantioselective cyclopropanation of styrene |
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| Authors: | SHI Min JIANG Jian-KangLaboratory of Organometallic Chemistry |
| Affiliation: | SHI,Min JIANG,Jian-KangLaboratory of Organometallic Chemistry,Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200032,China |
| Abstract: | A new class of chiral pyrrolidine ligands have been successfully synthesized and their chiral induction abilities have been examined in the homogeneous catalytic enantioselective cyclo-propanation of styrene. 15-30% enantiomeric excess ( ee) has been achieved. |
| Keywords: | Chiral ligand pyrrolidine enantioselective cyclopropanation catalyst |
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