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Vibrational interaction potentials
Authors:Y von Bergen  R von Bergen  B Linder
Institution:1. Department of Chemistry, Simon Bolivar University, Apartado 80659, Caracas, Venezuela
2. Department of Chemistry, The Florida State University, 32306, Tallahassee, FL, USA
Abstract:An expression is derived for the interaction potential arising from the correlative vibrational motion of fluctuating dipolar diatomic molecules, using as model the Morse oscillator. The theory is applied to two interacting NaCl molecules. The vibrational dipole-dipole coefficient,C 6, is strongly temperature dependent with a value at room temperature of 3.788 × 10?62 erg cm6.
Keywords:
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