| 液相氧化羰基化合成碳酸二乙酯的新型催化体系CuCl/1,10-菲罗啉/N-甲咪唑 |
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| 引用本文： | 莫婉玲,李光兴,朱永强,熊辉,梅付名.液相氧化羰基化合成碳酸二乙酯的新型催化体系CuCl/1,10-菲罗啉/N-甲咪唑[J].催化学报,2003,24(1):3-4. |
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| 作者姓名： | 莫婉玲 李光兴 朱永强 熊辉 梅付名 |
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| 作者单位： | DepartmentofChemistry,HuazhongUniversityofScienceandTechnology,Wuhan430074,Hubei,China |
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| 基金项目： | 华中科技大学校科研和教改项目，， |
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| 摘 要： | Diethyl carbonate (DEC) is one of the important green chemicals widely used for organic synthesis because of its various functional groups. DEC is a better octane blending fuel, and has more oxygen in the molecule than methyl tert-butyl ether (MTBE), 40.6% versus 18.2%, which reduces emissions from gasoline and diesel engine. For these reasons many studies on the production of DEC have been extensively carried out.
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| 关 键 词： | 碳酸二乙酯 催化体系 液相氧化羰基化 CuCl／1 10－菲罗啉／N－甲基咪唑 氯化亚铜 合成 |
| 收稿时间： | 2003-01-25 |
A Novel Catalyst CuCl/1,10-Phenanthroline/N-Methylimidazole for the Oxidative Carbonylation of Ethanol to Diethyl Carbonate |
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| MO Wanling,LI Guangxing,Zhu Yongqiang,XIONG Hui,MEI Fuming.A Novel Catalyst CuCl/1,10-Phenanthroline/N-Methylimidazole for the Oxidative Carbonylation of Ethanol to Diethyl Carbonate[J].Chinese Journal of Catalysis,2003,24(1):3-4. |
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| Authors: | MO Wanling LI Guangxing Zhu Yongqiang XIONG Hui MEI Fuming |
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| Abstract: | Diethyl carbonate (DEC) is one of the important green chemicals widely used for organic synthesis because of its various functional groups. DEC is a better octane blending fuel, and has more oxygen in the molecule than methyl tert-butyl ether (MTBE), 40.6% versus 18.2%, which reduces emissions from gasoline and diesel engine. For these reasons many studies on the production of DEC have been extensively carried out. |
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| Keywords: | ethanol oxidative carbonylation diethyl carbonate |
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