alpha-Substituted acylsilanes via a highly selective [1,4]-Wittig rearrangement of alpha-benzyloxyallylsilane |
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| Authors: | Onyeozili Edith N Maleczka Robert E |
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| Affiliation: | Department of Chemistry, Michigan State University, 540 Chemistry, East Lansing, Michigan 48824, USA. |
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| Abstract: | alpha-Benzyloxyallylsilane undergoes efficient [1,4]-Wittig rearrangement to generate an enolate intermediate that can be trapped with various electrophiles, thereby providing a new synthetic approach to substituted acylsilanes. |
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