Amplification of chirality in benzene tricarboxamide helical supramolecular polymers |
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| Authors: | Wilson Andrew J van Gestel Jeroen Sijbesma Rint P Meijer E W |
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| Institution: | Laboratory of Macromolecular and Organic Chemistry, Eindhoven University of Technology, PO Box 513, 5600 MB, Eindhoven, The Netherlands. |
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| Abstract: | The chirality of benzene tricarboxamides is expressed and amplified into the helicity of self-assembled columnar aggregates according to 'sergeants and soldiers' and 'majority rules' principles; the strength of the amplification is analysed quantitatively and the effect of the number of chiral groups in the sergeants is studied. |
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