Synthesis of derivatives of (S)-2-alkanols, components of pheromones ofDrosophila mulleri andRhyzopertha dominica, from (S)-(+)-3,7-dimethylocta-1,6-diene |
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| Authors: | G Yu Ishmuratov R Ya Kharisov O V Botsman V V Zorin G A Tolstikov |
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| Institution: | (1) Institute of Organic Chemistry, Ufa Research Center of Russian Academy of Sciences, 71 prosp. Oktyabrya, 450054 Ufa, Russian Federation;(2) Ufa State Petroleum Technical University, 1 ul. Kosmonavtov, 450062 Ufa, Russian Federation |
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| Abstract: | Effective routes for the synthesis of (S)-2-acetoxytridecane, the sex pheromone of the fruit flyDrosophila mulleri, and (S)-1-methylbutyl 2-methyl- and 2,4-dimethylpent-2E-enoates, components of the aggregation pheromone of the lesser grain borerRhyzopertha dominica, were developed on the basis of (S)-4-methylhex-5-en-1-yl tosylate accessible from (S)-(+)-dihydromyreene.
Published inIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 1929–1931, November, 2000. |
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| Keywords: | (S)-2-acetoxytridecane (S)-tridec-2-yl acetate (S)-(+)-3 7-dimethylocta-1 6-diene dominicalur (S)-4-methylhex-5-en-1-ol (S)-pentan-2-ol cross-coupling Baeyer-Villiger reaction Wacker-Tsuji reaction pheromone |
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