|
|||||
|
|
Transformation of solvent-derived ozonolysis products to bicyclic peroxides: Isolation and characterisation of novel pentoxonane derivatives |
|
| Authors: | Yoshihiro Ushigoe Shogo Tanaka Masatomo Nojima Kevin J McCullough |
| Institution: | Department of Chemical Process Engineering, Osaka University, Suita, Osaka 565, Japan Department of Chemistry, Heriot-Watt University, Edinburgh, EH14 4AS, Scotland |
| Abstract: |  -Hydroperoxyisochroman derivatives 5 react with formaldehyde under acidic conditions to produce mixtures of bicyclic 1,2,4,6-tetroxepane 9 and 1,2,4,6,8-pentoxonane 10 derivatives. The structure of the compound 10a was unambiguously established by the X-ray analysis. With acetaldehyde, only the corresponding 1,2,4,6-tetroxepanes 9 were obtained. |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ | |