A general cocatalyst strategy for performance enhancement in nickel catalyzed ethylene (co)polymerization |
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Institution: | CAS Key Laboratory of Soft Matter Chemistry, Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei 230026, China |
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Abstract: | The tuning of olefin-polymerization catalyst properties through ligand modifications is efficient but requires complicated and costly syntheses. In this contribution, a simple Bu2Mg-based cocatalyst strategy is designed that can simultaneously enhance the catalytic properties (activity, thermal stability, polymer molecular weight, branching density, melting point, etc.) of various nickel catalysts (α-diimine nickel, pyridine imine nickel and iminopyridine-N-oxide nickel) in ethylene polymerization, and enable great product morphology control. For example, a simple α-diimine nickel catalyst can demonstrate polymerization activity of up to 1.29×107 g mol?1 h?1 and molecular weight of up to 1.90×106 g/mol in the presence of Bu2Mg cocatalyst. The resulting polyethylenes exhibit excellent mechanical properties, with tensile stress of up to 47.4 MPa and strain of up to 1020%. This cocatalyst strategy is generally applicable to different nickel catalysts, and can lead to property enhancement in ethylene copolymerization with a series of polar comonomers such as methyl 10-undecylenate, 10-undecylenic acid and 10-undecenol. |
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