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Complexes d''addition des metaux halocarbonyle et halonitrosyle avec les acides de lewis |
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| Authors: | Marek Pakowski,Michaë l Bigorgne |
| Affiliation: | Laboratoire de Chimie de Coordination, Ecole Nationale Supérieure de Chimie de Paris, 11, rue Pierre et Marie Curie, 75231 Paris Cédex 05 France Institut Français du Pétrole, 1 et 4, Avenue du Bois Préau, 92502 Rueil-Malmaison France |
| Abstract: | This work deals with the reactions of metal carbonyl-halide adducts with Lewis acids [M(X → Lewis acid)(CO)aLb (L = PR3, π-Cp)]. Results are given regarding electric conductivity measurements in solution and IR spectra, as well as the preparation and study of a new class of metal nitrosyl-halide adducts, [M(X → Lewis acid)(NO)aLb]. A classification of Lewis acids is attempted following their electron-acceptor properties. |
| Keywords: | To whom correspondence and requests for reprints should be directed. |
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