When bigger is better: intermolecular hydrofunctionalizations of activated alkenes catalyzed by heteroleptic alkaline Earth complexes |
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| Authors: | Liu Bo Roisnel Thierry Carpentier Jean-François Sarazin Yann |
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| Affiliation: | Institut des Sciences Chimiques de Rennes, UMR CNRS-Université de Rennes, Campus de Beaulieu, France. |
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| Abstract: | New alkaline-earth amido complexes catalyze the regioselective intermolecular hydroamination (see scheme; Ae=alkaline earth) and hydrophosphination of styrene and isoprene with unprecedented activities. The catalytic performances increased linearly with the size of the metal. |
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| Keywords: | alkaline‐earth metals barium homogeneous catalysis hydroamination ligand design |
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