| 中性载体ETH1616推动质子在油／水界面的转移 |
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| 引用本文： | 汪尔康,吴亚英.中性载体ETH1616推动质子在油／水界面的转移[J].高等学校化学学报,1991,12(9):1160-1163. |
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| 作者姓名： | 汪尔康 吴亚英 |
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| 作者单位： | 中国科学院长春应用化学研究所电分析化学开放研究实验室，上海工业大学化学化工系，上海工业大学化学化工系，中国科学院长春应用化学研究所电分析化学开放研究实验室 长春 130022，长春 130022 |
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| 摘 要： | 本文用循环伏安法和循环电流扫描计时电位法研究了中性载体ETH1616(N,N-bjs-heptylethyldiamide)推动质子在油/水界面的转移过程,探讨了有关转移过程的机理,测定了相应的扩散系数和配合物的稳定常数。
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| 关 键 词： | 中性载体 质子转移 油 界面 水 |
The Proton Transfer Across Water/Oil Interface Facilitatited by Neutral lonophore ETH1616 |
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| Wang Er-kang,Wu Ya-ying,Qi De-yao,Yu Ze-mu.The Proton Transfer Across Water/Oil Interface Facilitatited by Neutral lonophore ETH1616[J].Chemical Research In Chinese Universities,1991,12(9):1160-1163. |
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| Authors: | Wang Er-kang Wu Ya-ying Qi De-yao Yu Ze-mu |
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| Abstract: | The proton transfer across the water/ nitrobenzene interface facilitated by ionophore ETH1616(N,N-bis heptyl-ethyldiamide) has been investigated by chronopotentiometry with linear current scanning and cyclic voltammetry. The stability constant of the complex and the diffusion coefficient of ionophore ETH1616 in the nitrobenzene phase have been estimated, respectively. The mechanism of the proton transfer has been discussed. |
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| Keywords: | Neutral ionophore Water/oil interface N N-bis-heptyl-ethyldiamide Proton transfer |
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