Highly efficient synthesis of optically pure 5,5',6,6',7,7',8,8'-octahydro-1,1'-bi-2-naphthol and -naphthylamine derivatives by partial hydrogenation of 1,1'-binaphthyls with carbon nanofiber supported ruthenium nanoparticles |
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Authors: | Takasaki Mikihiro Motoyama Yukihiro Yoon Seong-Ho Mochida Isao Nagashima Hideo |
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Affiliation: | Graduate School of Engineering Sciences, Institute for Materials Chemistry and Engineering, Kyushu University, Kasuga, Fukuoka 816-8580, Japan. |
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Abstract: | Use of Ru/CNF-P, nanoruthenium particles dispersed on a nanocarbon fiber support, realizes highly efficient catalytic partial hydrogenation of 1,1'-bi-2-naphthol and -naphthyl-amine derivatives. The reactions proceed in high turnover numbers without racemization of the axial chirality, offering a practical procedure for the production of optically pure 5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyls in good to high yields. |
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