Remarkable axial ligand effect on regioselectivity towards terminal alkenes in epoxidation of dienes by a robust manganese porphyrin |
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| Authors: | Lai Tat-Shing Lee Stephen K S Yeung Lam-Lung Liu Hai-Yang Williams Ian D Chang Chi K |
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| Affiliation: | Department of Chemistry and Open Laboratory of Chemical Biology, Institute of Molecular Technology for Drug Discovery and Synthesis, Hong Kong University of Science and Technology, Clear Water Bay, Hong Kong, PR China. |
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| Abstract: | With a highly encumbered manganese porphyrin as catalyst, significant improvements in regioselectivity towards less substituted C-C double bond in diene epoxidation were attained by simply adding organic bases as axial ligand. |
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