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Application of Thermal Analysis in Radiocarbon Dating
Authors:Brandova  D.  Maciejewski  M.  Keller  W. A.
Affiliation:(1) Department of Geography, University of Zurich, Winterthurerstrasse 190, 8057 Zurich, Switzerland;(2) Laboratory of Technical Chemistry, Swiss Federal Institute of Technology, ETH Zentrum, 8092 Zurich, Switzerland
Abstract:Thermal analysis combined with mass spectrometry was applied to radiocarbon dating procedures (age determination of carbon containing samples) to determine the optimal temperature range for the reduction of CO2 over metallic cobalt of various particle sizes. Experiments were carried out to show the different catalytic activities of cobalt of particle sizes 1, 1–45 and 44 μm. The morphology of the cobalt samples and the deposited carbon were investigated. The quantification of CH4 and CO formed during the reduction of CO2 was done by means of pulse thermal analysis. This revised version was published online in July 2006 with corrections to the Cover Date.
Keywords:pulse thermal analysis  thermal analysis in radiocarbon dating
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