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Stevens Rearrangement of Anilinium Salts By the Action Sodium Carbonate Hexahydrate
Authors:Shakhbazyan  L. G.  Babakhanyan  A. V.  Grigoryan  Dzh. V.  Kocharyan  S. T.
Affiliation:(1) Institute of Organic Chemistry, National Academy of Sciences of Armenia, Erevan, Armenia;(2) Abovyan Armenian State Pedagogical University, Erevan, Armenia
Abstract:Anilinium salts containing an allyl-like group together with various functionally substituted receiving groups undergo Stevens rearrangement by the action of sodium carbonate hexahydrate in the absence of a solvent. As a result, both N-methylaniline derivatives and nucleophilic substitution products are formed.
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