Stevens Rearrangement of Anilinium Salts By the Action Sodium Carbonate Hexahydrate |
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Authors: | Shakhbazyan L. G. Babakhanyan A. V. Grigoryan Dzh. V. Kocharyan S. T. |
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Affiliation: | (1) Institute of Organic Chemistry, National Academy of Sciences of Armenia, Erevan, Armenia;(2) Abovyan Armenian State Pedagogical University, Erevan, Armenia |
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Abstract: | Anilinium salts containing an allyl-like group together with various functionally substituted receiving groups undergo Stevens rearrangement by the action of sodium carbonate hexahydrate in the absence of a solvent. As a result, both N-methylaniline derivatives and nucleophilic substitution products are formed. |
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