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Racemic iron(III) and cobalt(III) complexes containing a new pentadentate "helmet" phthalocyaninato ligand
Authors:Kieler Heidi M  Bierman Matthew J  Guzei Ilia A  Liska Peter J  McGaff Robert W
Institution:Department of Chemistry, University of Wisconsin-La Crosse, 1725 State Street, La Crosse, WI 54601, USA.
Abstract:Solvothermal reactions of iron(II) acetate tetrahydrate and cobalt(II) acetate tetrahydrate with 1,2-dicyanobenzene in methanol solution result in the formation of racemic six-coordinate iron(III) and cobalt(III) complexes, respectively, with a new bicyclic pentadentate 14,28-1,3-diiminoisoindolinato]phthalocyaninato ligand.
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