Synthesis of big palladium clusters. Preparation of Pd23(CO)20(PEt3)8 |
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Authors: | E G Mednikov |
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Institution: | (1) Instutute of the Chemistry of Carbon Materials, Russian Academy of Sciences, Kemerovo, Russian Federation |
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Abstract: | Selective methods for the synthesis of the cluster Pd23(CO)20L8, L=PEt3, have been suggested. The compound has been prepared by two routes: by the reaction of Pd10(CO)12L6 with Me3NO in the presence of HOAc with removal of CO from the gas phase, and by the reaction of Pd10(CO)12L6 with Pd(OAc)2 and CO followed by oxidation by Me3NO in an inert atmosphere.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1299–1300, July, 1993. |
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Keywords: | palladium clusters synthesis |
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