A simple method for the alpha-oxygenation of aldehydes |
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| Authors: | Beshara Cory S Hall Adrian Jenkins Robert L Jones Teyrnon C Parry Rachael T Thomas Stephen P Tomkinson Nicholas C O |
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| Affiliation: | School of Chemistry, Cardiff University, PO Box 912, Cardiff, CF10 3TB, UK. |
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| Abstract: | A mild, efficient and general method for the chemospecific alpha-oxygenation of aldehydes is described. Treatment of a series of aldehydes with N-tert-butyl-O-benzoyl hydroxylamine hydrochloride gives the corresponding alpha-oxygenated carbonyl via a proposed pericyclic rearrangement process. |
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