| Charge-transfer Salt of Tungstogermanate Heteropolyanion and Dibenzotetrathiofulvalene |
| |
| 作者姓名： | CHEN Ya-Guang LIU Jing-Fu XING Yan LIN Yong-Hua JIA Heng-Qing |
| |
| 作者单位： | CHEN Ya-Guang; LIU Jing-Fu; XING Yan;LIN Yong-Hua ;JIA Heng-Qing(Department of Chemistry，Northeast Normal University，Changchun 1 30024 )(Changchun Institute of Applied Chemistry，the Chinese Academyof Sciences，Changchun 130022) |
| |
| 摘 要： | lINTRODUCTIONSincetheobservationofametallicstateinthechargetransfer(CT)salt,(TTF)(TCNQ)(l:(TTF=tetrathiofulva1eneiTCNQ=7,7,"8,8-tetracyano-p-quin-odimethane)andasuperconductingstateintheBechgaardsaltsF27,(TMTSF)2X,2EXPERIMENTAL2'1Preparati0n0fchargetransfersaltThedbtf(C,'H,S')wasobtainedac-cordingtoreference6iandexaminedby1HNMRspectrosc0py.t(C'H,)'Nj'GeW,,-O',waspreparedaccordingtoreferencet73andcheckedwithIRspectraandpolaro-graphicmethods.TheCTsaltwassynthesizedbyco…
|
Charge-transfer Salt of Tungstogermanate Heteropolyanion and Dibenzotetrathiofulvalene |
| |
| CHEN Ya-Guang, LIU Jing-Fu, XING Yan,LIN Yong-Hua ,JIA Heng-Qing.Charge-transfer Salt of Tungstogermanate Heteropolyanion and Dibenzotetrathiofulvalene[J].Chinese Journal of Structural Chemistry,1998(2). |
| |
| Authors: | CHEN Ya-Guang LIU Jing-Fu XING Yan LIN Yong-Hua JIA Heng-Qing |
| |
| Abstract: | Charge-transfer salt (dbtf),HGeW12O40. 4H2O(C84H57O44S24GeW12)was synthesized by electrocrystallization and characterized by IR and electronic spectra.Its magnetic and conducting properties and crystal structure were determined. The titlesalt crystallized in triclinic system with P1 space group. Its cell parameters are reflexions |
| |
| Keywords: | crystal structure synthesis tungstogermanate dibenzotetrathiofulvalene |
| 本文献已被 CNKI 等数据库收录！ |
